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Creating Sustainable CO2 Value Chain, Industry 4.0 Opportunities

(in lingua inglese)

- Saipem has the capability in terms of innovation, engineering, construction and installation to take care of the whole EPCI CCUS value chain;
- Proprietary CO2 separation process schemes are under development and will be ready for start up and demonstration testing in 2-3 year time;
- Namely Saipem has executed in the past years a number of different initiatives in terms of studies, Front Ends a EPC projects related to CO2 capture, transportation and injection;
- Synergies with large scale H2 production are envisioned for CCS: SAIPEM offers a single-point responsibility for complex integrated solutions;
- INDUSTRY 4.0 offers opportunities with high economic potential associated with digital interconnection through innovation, efficiency, sustainability, supply chain management and manufacturing.

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mcT Petrolchimico Milano novembre 2017 Petrolchimico 4.0: tecnologie innovative per la progettazione e la conduzione degli impianti

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da Alessia De Giosa
mcT Petrolchimico Milano 2017Segui aziendaSegui




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Milano, 30 novembre 2017 Gli atti dei convegni e più di 8.000 contenuti su www.verticale.net November 2017 1 lunedì 4 dicembre 2017 TRANSPORTATION DOWNSTREAM EMITTER UPSTREAM EMITTER AGI ' EOR EGR - ECBM ENERGY CONVERSION REUTILIZATION mcT Petrolchimico, 30 Novembre 2017
'Petrolchimico 4.0: tecnologie innovative per la
progettazione e la conduzione degli impianti"
Creating Sustainable CO2 Value Chain,
Industry 4.0 Opportunities
Renewable Technologies & Innovation DPT
De Rinaldis Salvatore
Nettuno Francesco
Lepore Alessandro
November 2017 2 ' RENEWABLES AND INNOVATION ' SAIPEM COMPLETE SUSTAINABLE CO2 VALUE CHAIN
' MARKET ' CAPTURE TECHNOLOGIES ' INNOVATION IN CCUS PROCESSES ' CO2 MANAGEMENT ' CCUS COMBINED WITH CLEAN H2 VALUE CHAIN ' INDUSTRY 4.0 OPPORTUNITIES ' CONCLUSIONS AGENDA November 2017 3 PRESENT AREA OF INEREST ' NON-CONVENTIONAL CO2 REMOVAL TECHNOLOGIES ' SOLUTIONS FOR CO2 REUTILIZATION & CONVERSION ' CO2 TRANSPORT & STORAGE RENEWABLE TECHNOLOGIES ' CONCENTRATING SOLAR
POWER APPLICATIONS ' BIO-REFINERIES ' BIO-PRODUCTS ' WTE SOLUTIONS ' GEOTHERMAL ENERGY ' WIND ' SOLAR ' HYDRO & REVERSE PUMP ' ENERGY MANAGEMENT ' EN. EFFICIENCY SOLUTIONS ' INNOVATIVE TECHNOLOGIES
FOR POWER GENERATION ' CO2 POWER CYCLE ' FLARE GAS RECOVERY ' FUEL CELL ENERGY STORAGE TECHNOLOGIES ENERGY SOLUTIONS
AND
TECHNOLOGIES CO2 VALUE CHAIN TECHNOLOGIES ' H2 STORAGE TECH'S ' THERMAL STORAGE ' CRYOGENIC STORAGE ' SOLID STORAGE ' HYDRATES STORAGE ' METAL ORGANIC FRAMEWORK ' SUPER CAPACITOR ' BATTERY ' MARKET TREND ANALYSIS ' TECHNOLOGY SCOUTING ' TECHNOLOGY DEVELOPMENT ' BUSINESS DEVELOPMENT RENEWABLES AND INNOVATION November 2017 4 Process Gas Flue Gas Flue Gas Process Gas Gas Field Flue Gas Flare FLUE GAS CO2 CONTENT: =15% PROCESS GAS CO2 CONTENT: =10÷40% GAS FIELD CO2 CONTENT: =15÷80% Sources of CO2 SAIPEM COMPLETE SUSTAINABLE CO2 VALUE CHAIN
MARKET ASSESSMENT
Gas Field November 2017 5 SAIPEM COMPLETE SUSTAINABLE CO2 VALUE CHAIN
MARKET, TECHNOLOGIES AND INNOVATION SUSTAINABILITY
TRANSPORTATION DOWNSTREAM EMITTER UPSTREAM EMITTER AGI ' EOR EGR - EGS ENERGY CONVERSION REUTILIZATION new capture tech's needed
to exploit new market
Carbon Tax pending new CCUS processes advanced large scale
energy value chain concept
synergy with other
CO2 value chain branches
new tech's & architectures new CCUS processes ' AGI : Acid Gas Injection
' EOR : Enhanced Oil Recovery
' EGR : Enhanced Gas Recovery
' EGS : Enhanced Geothermal System synergy with other
CO2 value chain branches
new tech's & architectures To extract value from Data November 2017 6 ' ACQUEOUS SOLVENTS ABSORPTION (AMINE, AMMONIA) ' NON-ACQUEOUS SOLVENTS ABSORPTION ' ALL MEMBRANE FOR PRETREATMENT AND SEPARATION ' CRYO-TECHNOLOGIES ' HYBRID CRYO-MEMBRANE ' SAIPEM PROPRIETARY PROCESS SCHEMES BASED ON CRYOGENIC TECHNOLOGIES ' Lower Capex ' Lower Opex ' Pumpable CO2 stream PROS ' Technology not
commercially available
yet: 2-3 years to
Market (TRL6-4) CONS Most common method 3rd party technology Low CAPEX method 3rd party technology CAPTURE TECHNOLOGIES SAIPEM COMPLETE SUSTAINABLE CO2 VALUE CHAIN November 2017 7 Treated
Gas
100 t/h Feed Gas with CO2 CO2
Rich Gas
150 t/h Outlet Compressor * CO2 Removal Unit (= 35% CO2, 200 MMSCFD): ' Gas Field Feasibility Application ' Package size is 17m x 17m x 8m ' Estimated weight of ~400 ton P-Guard membrane Polymeric membrane JT Valve Separator HEX HEX Condensate to pipeline Water * Saipem experience/feasibility with turbomachinery manufacturer 3rd Party SAIPEM COMPLETE SUSTAINABLE CO2 VALUE CHAIN
CAPTURE TECHNOLOGIES: ALREADY AVALILABLE (3rd Party)
November 2017 8 Treated
Gas 50 t/h Feed Gas with CO2 Cryogeni Unit 3rd Party CO2 Rich Gas 300 t/h
(liquid) Membrane 3rd Party CO2 Compressor * Permeate Compressor * Sales Gas Compressor * CO2 Removal Unit (= 35% CO2, 200 MMSCFD): ' Gas Field Feasibility Application ' Package size is 20m x 20m x 20m ' Estimated weight of ~700 ton SAIPEM COMPLETE SUSTAINABLE CO2 VALUE CHAIN
CAPTURE TECHNOLOGIES: ALREADY AVALILABLE (3rd Party)
* Saipem experience/feasibility with turbomachinery manufacturer November 2017 9 ' Emerging technology aimed to deliver lower CAPEX/OPEX, this technology can be
applied to: ' CryoCO2 process scheme for Flue Gas : 2 years to Market (TRL6)* ' CryoCO2 process scheme for Syngas : 3 years to Market (TRL4)* ' CryoCO2 process scheme for Gas Field : 3 years to Market (TRL4)* ' Reduction of feed gas CO2 content down to 2÷5% ' Very low PRODUCT losses (< 1÷2%) ' High flexible with CO2 percentage in the feed gas ' The PRODUCT treated gas stream can be completely liquid at high pressure and
therefore is envisioned to be suitable for LNG or LH2 production (under evaluation) ' Produces liquid CO2 pumped to required pressure for transport or local reinjection
for transport or local re-injection TRL : Technology Readness Level, TRL 1 ' basic principles observed , TRL 9 ' actual system proven in operational environment * Based on budget plan SAIPEM COMPLETE SUSTAINABLE CO2 VALUE CHAIN
SAIPEM CAPTURE TECHNOLOGIES: UNDER DEVELOPMENT
November 2017 10 Pipelines design and construction, flow assurance, supercritical pipeline,
dense phase CO2 transport, high pressure transport, analysis of
depressurization.
Capabilities Projects Brindisi ' Italy, Supercritical CO2 Pipeline
FEED: Basic design of a test-loop for CO
2 flow properties investigation, FEED for a pilot dense phase CO2 transportation system. Ras Laffan Complex - Qatar, CO2 Reinjection
EPC Project: 750 MMSCFD of CO
2 Removal. Compression at 120 bar and delivery of 90 MMSCFD of CO2 to injection wells at 1500 m depth. Mellitah ' Lybia, CO 2 Capture, Transport and Injection Feasibility Study: treatment, compression, transportation of CO2. Different options studied, 525 km pipeline with recompression up to 180 bar, 120 km
sealine with CO2 injection to wellheads, 140 km pipeline and injection to wellheads at
289 bar. SAIPEM CAPABILITIES: TRANSPORT AND STORAGE CO2 MANAGEMENT November 2017 11 CO2 MANAGEMENT
SAIPEM SKILLS AND KNOWLEDGE
AGI ' CO2, H2S Re-injection EPC Project: RasGas, Ras Laffan Complex (Qatar) EOR pilot plant in existing refinery
Proposal for EPC: ENI, Armatella (Italy)
CO2 Capture and Sequestration Study: ENI E&P and Mellitah O&G BV Supercritical CO2 Pipeline Transportation Study: ENI/ENEL, Brindisi - Italy CO2 Removal from Syngas in Ammonia-Urea Complex EPC Projects: Engro, Omifco, Qafco and Dangote CO2 Removal from Syngas in IGCC EPC Projects: ENI, ISAB Energy, Sarlux and ARAMCO CO2 Removal in Gas Treatment Plant EPC Projects: Gasco, Aramco and Agip Gas Pilot Dense Phase CO2 Transport Loop FEED: ENI/ENEL, Brindisi - Italy CONVENTIONAL CO2 MANAGEMENT ADVANCED CO2 MANAGEMENT OXY Burner Technology, CCS Chain Demonstration
EPC: Total, Lacq - France
November 2017 12 ' HYDROGEN Novel combination of commercially available technologies for hydrogen production starting from
flare gas, solid and liquid waste.
Pure CO2 stream can be easily addressed to re-utilization processes or simply re-injection. ' UREA Novel combination of commercially available technologies for hydrogen production starting from
flare gas, solid and liquid waste. In addition captured CO2 can be reused for UREA production. ' METHANOL Novel combination of commercially available technologies for hydrogen production starting from
flare gas, solid and liquid waste. In addition captured CO2 can be reused for methanol production. ' Other INNOVATION IN CCUS PROCESSES
PROPRIETARY Schemes: WASTE TO PRODUCT
' Power Electric, Thermal Power or Steam with CO2 ready for CCUS : SAIPEM PROPRIETARY SCHEMES under development November 2017 13 H2 H2 Production CH4 CCUS 150 t/h SMR, ATR, POX H2 Liquefaction Surplus Renewable Energy Electrolysis Storage & Trasportation LH2 TANKS, H2 IN SALT CAVERN LH2 CARRIERS H2 PIPELINES SMR: Steam Methane Reforming H2 Capacity : 100,000-180,000 Nm3/h (1-2 step) ATR: Auto Thermal Reforming H2 Capacity : 1,000,000 Nm3/h POX: Partial Oxidation H2 Capacity : 80,000 Nm3/h Utilization REFUELLING STATIONS, FCEV HYDROGEN GTG, FC COMBINED CYCLE POWER PLANT CCUS COMBINED WITH CLEAN H2 VALUE CHAIN
SAIPEM TECHNOLOGIES
November 2017 14 SMR H2 Product * H2 Final Purification Natural Gas 3rd Party Clean Flue Gas CO2 Liquid CO2 Liquid SAIPEM PROPRIETARY PROCESS SCHEME under development Shift CO2 Liquid *3rd Party liquefaction packages CCUS COMBINED WITH CLEAN H2 VALUE CHAIN
SAIPEM TECHNOLOGIES
Scheme CryoCO2 Syngas Hybrid-Cryo Membrane Scheme CryoCO2 Flue Gas November 2017 15 2-step Shift CO2 Removal 2-step Reforming Natural
Gas or
Naphtha
CO2 Compr. Urea Plant CO2 NH3 P = 150 -160 bar H2 and CO2 More than 20 FULLY INTEGRATED ammonia-urea complexes PROJECT: QAFCO 5 PROJECT: OMIFCO Project Urea Plant Capacity H2 Produced CO2 Captured QAFCO 5 3850 t/day 180,000 Nm3/h 120 t/h OMIFCO 2530 t/day 150,000 Nm3/h 80 t/h H2 Methanator Synloop Wide Saipem experience in CO2 Compression CCUS COMBINED WITH CLEAN H2 VALUE CHAIN
SAIPEM REFERENCES FOR SYNGAS ' AMMONIA UREA PLANTS
Feed Pretreatment November 2017 16 Jazan IGCC Vacuum
Residue
Fuel Oil
Power 2.4 GW The overall IGCC project has been divided in six major packages. Saipem work packages are: ' Gasification Unit (15 gasifiers) ' Acid Gas Removal ' Hydrogen Recovery Unit ' Sour Water Stripper ' Soot Ash Removal Unit PACKAGE 1 (Pkg 1) ' Sulfur Recovery for IGCC ' Sulfur Recovery for Refinery ' Sulfur Storage PACKAGE 2 (Pkg 2) Pkg 1 Pkg 2 Equipment no. 1200 720 Structure ton 52000 15000 Piping steel ton 33000 10000 Piping no-steel ton 1200 350 E&I Cables km 4000 1200 Total I/O no. 44000 11000 Saipem quantities: 110,000 BPD H2 184'000 Nm3/h CCUS COMBINED WITH CLEAN H2 VALUE CHAIN
THE WORLD'S LARGEST RESIDUE GASIFICATION UNIT
High Potential for Digitalization in Manufacturing & Logistic Supply Chain Management November 2017 17 Offshore Wind Farm Electrolysis Storage Transport Hywind Scotland Project Offshore Wind Experience Hydrogen Handling Experience SAIPEM OFFERS A SINGLE-POINT RESPONSIBILITY FOR COMPLEX INTEGRATED SOLUTIONS H2 SAIPEM TECHNOLOGIES: WIND TO HYDROGEN CCUS COMBINED WITH CLEAN H2 VALUE CHAIN Smart Factories part of the Energy System: flexible use of energy November 2017 18 Auto Thermal Reformer Natural Gas H2 Feed Pretreatment SAIPEM TECHNOLOGIES: RENEWABLES TO HYDROGEN H2 O2 from ASU CCUS COMBINED WITH CLEAN H2 VALUE CHAIN Renewable Energy Electrolysis O2 Storage Transport Water Smart Factories part of the Energy System: flexible use of energy November 2017 19 INDUSTRY 4.0 OPPORTUNITIES: CO2 VALUE CHAIN
MARKET, TECHNOLOGIES AND INNOVATION SUSTAINABILITY
MARKET CCUS VALUE CHAIN DISRUPTIVE TECHNOLOGIES PROCESS OPTIMIZATION TECHNOLOGY PORTFOLIO OPERATION BIG DATA & ANALYTICS HORIZONTAL & VERTICAL INTEGRATION CLOUD PLATFORM ADDITIVE MANUFACTURING
SIMULATION
AUGMENTED REALITY
SUPPLY CHAIN MANAGEMENT
GIS TECHNOLOGIES
INDUSTRIAL INTERNET
SMART FACTORIES
FLEXIBLE USE OF ENERGY
November 2017 21 CONCLUSIONS ' Saipem has the capability in terms of innovation, engineering, construction and
installation to take care of the whole EPCI CCUS value chain; ' Proprietary CO2 separation process schemes are under development and will be ready for start up and demonstration testing in 2-3 year time; ' Namely Saipem has executed in the past years a number of different initiatives in
terms of studies, Front Ends a EPC projects related to CO2 capture, transportation
and injection; ' Synergies with large scale H2 production are envisioned for CCS: SAIPEM offers a single-point responsibility for complex integrated solutions; ' INDUSTRY 4.0 offers opportunities with high economic potential associated with
digital interconnection through innovation, efficiency, sustainability, supply chain
management and manufacturing. November 2017 22 22 lunedì 4 dicembre 2017 Thank You for Your Attention Website : www.saipem.com


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